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 |  موضوع: كتاب Responsive Materials and Methods الخميس 17 يناير 2019, 12:10 pm | |
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أخوانى فى الله
أحضرت لكم كتاب
Responsive Materials and Methods
State-of-the-Art Stimuli Responsive Materials and Their Applications
من سلسلة علم المواد المتقدمة
Advanced Material Series
Edited by
Ashutosh Tiwari and Hisatoshi Kobayashi
ويتناول الموضوعات الأتية :
Contents
Preface xiii
PART 1 Stimuli-Responsive Polymeric Materials 1
1 Smart Thermoresponsive Biomaterials 3
Mohammed Yaseen and Jian R. Lu
1.1 Introduction 3
1.2 Temperature-Responsive Polymers 5
1.2.1 Thermoresponsive Polymers Based on LCST 5
1.2.2 Biopolymers and Artificial Polypeptides 8
1.2.3 Temperature Sensitivity of Polymers 8
1.3 Development of Thermoresponsive Surfaces 10
1.3.1 Surface Modifications Using
Energetic Oxidation 10
1.3.2 Surface Grafting of Polymers 13
1.3.3 Graft Polymerization 14
1.4 Surface Characterization 15
1.5 Cell Culture and Tissue Engineering
Applications 16
1.6 Chromatography 20
1.7 Conclusion 22
References 22
2 Light-Triggered Azobenzenes: From Molecular
Architecture to Functional Materials 27
Jaume Garcia-Amor?s and Dolores Velasco
2.1 Why Light-Triggered Materials? 28
2.2 Azobenzene-Based Light-Activatable
Materials 29vi Contents
2.3 Photoswitchable Azobenzene-Based Materials 31
2.3.1 Photochromic Switches Based on
Azobenzene-Doped Liquid Crystals 31
2.3.2 Photochromic Oscillators Based on
Fast Thermal Isomerizing Azo Dyes 37
2.3.3 Fast Isomerizing Azobenzenes and Their
Potential Use for Biological Applications 39
2.3.4 Photoelectronic Switches Based on Azo Dyes 43
2.4 Photodeformable Azobenzene-Based Materials:
Artificial Muscle-like Actuation 47
2.5 Conclusion and Perspectives 53
Acknowledgements 54
References 54
3 Functionalization with Interpenetrating Smart
Polymer Networks by Gamma Irradiation for
Loading and Delivery of Drugs 59
Franklin Mu?oz-Mu?oz and Emilio Bucio
Abbreviations 60
3.1 Introduction 61
3.2 General Concepts 63
3.2.1 Graft Copolymers and Ionizing Radiation 63
3.2.2 Methods of Radiation for Preparing Grafts 65
3.3 Radiation Synthesis and Modifi cation of Polymers
(Approaches) 74
3.3.1 Thermosensitive Networks 75
3.3.2 pH-Sensitive Networks 76
3.3.3 IPNs 77
3.3.4 Graft Copolymers 80
Acknowledgements 88
References 88
4 Biomedical Devices Based on Smart Polymers 105
Angel Contreras-Garc?a and Emilio Bucio
4.1 Introduction 106
4.2 Stimuli Responsive Polymers 107
4.3 Sensitive Hydrogels 108
4.4 Responsive Materials for Drug Delivery Systems 109Contents vii
4.5 Intelligent Polymers for Tissue Engineering 112
4.6 Types of Medical Devices 113
Acknowledgements 117
References 117
5 Stimuli-Responsive Polymers as Adjuvants and
Carriers for Antigen Delivery 123
Akhilesh Kumar Shakya and Kutty Selva Nandakumar
Abbreviations 124
5.1 Introduction 124
5.2 Responsive Polymers as Antigen Carriers 129
5.2.1 Charge Responsive Carrier 129
5.2.2 Oxidation Responsive Carrier 129
5.2.3 pH-Responsive Carrier 130
5.2.4 Temperature-Responsive Carrier 131
5.3 Factors Affecting Adjuvant Potential of
Stimuli-Responsive Polymeric Adjuvant 135
Acknowledgements 136
References 136
6 Cyclodextrins as Advanced Materials for
Pharmaceutical Applications 141
Vesna D. Nikolic, Ljubisa B. Nikolic, Ivan M. Savic, and
Ivana M. Savic
6.1 Inclusion Complexes 142
6.2 Preparation of Inclusion Complexes 143
6.3 Historical Development of Cyclodextrins 145
6.4 Equilibrium 149
6.5 Confirmation of Formed Inclusion Complexes 152
6.6 Application of Cyclodextrins in the Pharmacy 153
6.7 Cyclodextrins as a Drug Delivery System 154
6.8 Cyclodextrin as Solubilizers 157
6.9 Pharmaceutical Formulation
Containing Cyclodextrin 158
6.10 Conclusion 160
References 161viii Contents
PART 2 Smart Nano-Engineered Materials 167
7 Advances in Smart Wearable Systems 169
Rajesh Kumar Saini, Jaya Bajpai, and A. K. Bajpai
7.1 Introduction 170
7.2 Classification of Smart Polymers 172
7.2.1 Shape-Memory Polymers 173
7.2.2 Conducting Polymers 175
7.2.3 Stimuli-Responsive Hydogels 177
7.2.4 Nanomaterials 179
7.3 Applications 181
7.3.1 Smart Fabrics 182
7.3.2 Smart Skin 185
7.3.3 Biosensors 189
7.4 Current Features of Wearable Systems 192
7.5 Conclusions 194
7.6 Challenges and Future Prospects 194
References 195
8 Functionalization of Smart Nanomaterials 201
Sharda Sundaram Sanjay and Avinash C. Pandey
8.1 Introduction 202
8.1.1 Importance of Functionalization 203
8.1.2 Advantages of Surface Functionalization 204
8.2 Functionalizing Agents 205
8.2.1 Mode/Ways to Surface Functionalization 206
8.2.2 Strategy for the Conjugation 206
8.2.3 Classification of Surface Functionalization
of Nanomaterials 207
8.2.4 Methodology 210
8.2.5 Conditions Favorable for
Biofunctionalization 213
8.3 Carbon Nanomaterials 217
8.3.1 Functionalization of Carbon Nanotubes 218
8.4 Silica Nanoparticles 224
8.5 Confirmation of Functionalization 225
8.5.1 Confirmation through Infrared
Spectral Analysis 225
8.5.2 Confirmation through Optical/
Colorimetric Assay 227Contents ix
8.5.3 Confirmation through Contact
Angle Measurement 228
8.5.4 Confirmation with the Help of
Metathesis Reactions 228
Acknowledgements 229
References 229
9 Role of Smart Nanostructured Materials in Cancers 237
Rizwan Wahab, Farheen Khan, Javed Musarrat, and
Abdulaziz A.Al-Khedhairy
9.1 Introduction 238
9.1.1 What is cancer? 238
9.1.2 Types of Cancers 239
9.1.3 Importance of Nanostructures 244
9.2 Experimental 246
9.2.1 Nanomaterials Synthesis 246
9.2.2 Characterizations of Synthesized
Nanomaterials 247
9.2.3 Biological Characterizations for the
Identifi cation of Cancers 251
9.3 Results Related to Use of Smart Nanostructured
Materials to Control Cancers Cells 258
9.4 Summary and Future Direction 265
Acknowledgement 266
References 266
10 Quantum Cutter and Sensitizer-Based Advanced
Materials for their Application in Displays,
Fluorescent Lamps and Solar Cells 273
Raghvendra Singh Yadav, Jaromir Havlica, and Avinash
Chandra Pandey
10.1 Introduction 274
10.2 Quantum Cutter and Sensitizer-Based
Advanced Materials 275
10.2.1 Visible Quantum Cutting 277
10.2.2 Near-Infra Red Quantum Cutting 284
10.3 Conclusion 297
Acknowledgement 297
References 298x Contents
11 Nanofibers of Conducting Polymer Nanocomposites 303
Subhash B. Kondawar and Shikha P. Agrawal
11.1 Conducting Polymers 304
11.2 Nanostructure Conducting Polymers 311
11.2.1 Conducting Polymer Nanocomposites 315
11.2.2 Nanofibers of Conducting Polymer
Nanocomposites 319
11.2.3 Electrospinning 326
11.2.4 Theoretical Modeling of Electrospun
Nanofibers 328
11.2.5 Electrospun Nanofibers of Conducting
Polymer Nanocomposites 333
11.3 Electrical Conductive Properties of Nanofibers
of Conducting Polymer Nanocomposites 337
11.4 Applications of Nanofi bers of Conducting
Polymers Nanocomposites 341
11.4.1 Supercapacitors 341
11.4.2 Rechargeable Batteries 343
11.4.3 Sensors 344
11.5 Concluding Remarks 347
References 348
PART 3 Smart Biosystems Engineering 357
12 Stimuli-Responsive Redox Biopolymers 359
Sudheesh K. Shukla and Ashutosh Tiwari
12.1 Introduction 359
12.2 Method of Synthesis, Characterization
and Mechanism 363
12.3 Stimuli-Responsive Redox and Electrical
Conductive Behavior 367
12.4 Biosensor Applications 372
12.5 Conclusion 373
References 374Contents xi
13 Commodity Thermoplastics with Bespoken
Properties using Metallocene Catalyst Systems 377
Nikhil Prakash
13.1 Introduction 378
13.2 Metallocene Catalyst Systems 379
13.2.1 Evolution of the Metallocenes 381
13.2.2 Categories of Metallocene Catalysts 382
13.2.3 Cocatalysts 383
13.3 Metallocene Thermoplastics 385
13.3.1 Polyethylene: Manufacture, Structure
and Properties 385
13.3.2 Polypropylene: Manufacture, Structure
and Properties 387
13.3.3 Polystyrene 391
13.4 Conclusions and Future Prospects 393
References 393
PART 4 Theory and Modeling 397
14 Elastic Constants, Structural Parameters and Elastic
Perspectives of Thorium Mono-Chalcogenides in
Temperature Sensitive Region 399
Krishna Murti Raju
Nomenclature 400
14.1 Introduction 400
14.1.1 Primer of the Field 401
14.1.2 Overview 402
14.2 Formulation 404
14.3 Evaluation 410
14.4 Results and Discussions 414
14.4.1 Higher Order Elastic Constants 415
14.4.2 Pressure Derivatives 419
14.5 Conclusions 424
Acknowledgment 424
References 424
Index 42
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